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Materials breakthrough: Alloy doesn't expand when heated

A metal alloy has been developed that shows practically no thermal expansion over an extremely large temperature interval.

Most metals expand when their temperature rises. The Eiffel Tower, for example, is around 10 to 15 cm taller in summer than in winter due to its thermal expansion. However, this effect is extremely undesirable for many technical applications.

For this reason, the search has long been on for materials that always have the same length regardless of the temperature. Invar (aka FeNi36 or 64FeNi in the U.S.), for example, a magnetic alloy of iron and nickel, is known for its extremely low thermal expansion. How this property can be explained physically, however, was not entirely clear until now.

[Credit: Image courtesy of Vienna University of Technology (TU Wien)]

 

 

A new collaboration between theoretical researchers at Vienna University of Technology (TU Wien) and experimentalists at the University of Science and Technology Beijing has led to a decisive breakthrough: Using complex computer simulations, they have made it possible to understand the invar effect in detail and thus develop a so-called pyrochlore magnet -- an alloy that has even better thermal expansion properties than Invar. Over an extremely wide temperature range of over 400 Kelvins, the new alloy's length changes by only around one-ten-thousandth of one percent per Kelvin.

Thermal expansion and its antagonist
"The higher the temperature in a material, the more the atoms tend to move -- and when the atoms move more, they need more space. The average distance between them increases," explains Dr. Sergii Khmelevskyi from the Vienna Scientific Cluster (VSC) Research Center at TU Wien. "This effect is the basis of thermal expansion and cannot be prevented. But it is possible to produce materials in which it is almost exactly balanced out by another, compensating effect."

Segii Khmelevskyi and his team developed complex computer simulations that can be used to analyze the behavior of the magnetic materials at finite temperature on the atomic level. "This enabled us to better understand the reason why Invar hardly expands at all," says Khmelevskyi. "The effect is due to certain electrons changing their state as the temperature rises. The magnetic order in the material decreases, causing the material to contract. This effect almost exactly cancels the usual thermal expansion."

It had already been known that the magnetic order in the material is responsible for the invar effect. However, only with the computer simulations from Vienna did it become possible to understand the details of this process so precisely that predictions for other materials could be made. "For the first time, a theory is available that can make concrete predictions for the development of new materials with vanishing thermal expansion," says Khmelevskyi.

The pyrochlore magnet with Kagome planes
In order to test these predictions in practice, Khmelevskyi worked together with the experimental team of Prof. Xianran Xing and Ass. Prof. Yili Cao from the Institute of the Solid State Chemistry of the University of Science and Technology Beijing. The result of this co-operation has now been presented; a material called a pyrochlore magnet.

In contrast to previous Invar alloys, which only consist of two different metals, the pyrochlore magnet has four components: zirconium, niobium, iron, and cobalt. "It is a material with an extremely low coefficient of thermal expansion over an unprecedentedly wide temperature range," says Cao.

This remarkable temperature behavior has to do with the fact that the pyrochlore magnet does not have a perfect lattice structure that always repeats itself in exactly the same way. The composition of the material is not the same at every point, it is heterogeneous. Some areas contain a little more cobalt, some a little less. Both subsystems react differently to temperature changes. This allows the details of the material composition to be balanced point by point in such a way that the overall temperature expansion is almost zero.

The material could be of particular interest in applications with extreme temperature fluctuations or precise measuring techniques, such as in aviation, aerospace, or high-precision electronic components. However, we will have to wait until there is more testing on the pyrochlore magnet material to find out what its key properties -- and limitations -- are.

Interested in more details about the research? See:

• "Predictive Theory of Anomalous Volume Magnetostriction in Fe-Ni Alloys: Bond Repopulation Mechanism of the Invar Effect," The Journal of Physical Chemistry.
• "Local chemical heterogeneity enabled superior zero thermal expansion in nonstoichiometric pyrochlore magnets," National Science Review.

Source: Vienna University of Technology (TU Wien)

Published February 2025

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